AMX DAS-M-0608 Manual de usuario descargar pdf (Pagina 134)

125

iH-NMR

(CDCI3,

200

MHz):

3,06

(s,

Iffl,

2

-N(CH3)2);

6,70

(AA'

(J0

=

8,9),

4H,

H-C(3),

H-C(5),

H-C(3'),

H-C(5'));

7,77

(XX'

(J0

=

9,1),

3H,

H-C(6),

H-C(2'),

H-C(6')).

Das

AA'XX'-System

ist

weniger

scharf

ds

im

Referenzspektrum

der

undeuterierten

Verbindung

65.

IR

(KBr):

2950m,

2920s,

2850m,

1595s,

1365m,

1320m,

1295m, 1275w,

1230m,

1200w,

1165m,

925m,

825w,

775w,

680w,

555w.

MS

(I>15%):

270(36),

269(M+,

100),

268(41),

255(19),

252(21),

226(15), 225(36),

150(19),

149(77),

148(78),

135(18), 134(27), 133(16),

121(39), 120(34),

119(27),

106(21),

105(33),

104(21), 92(18),

91(24),

85(21),

84(20), 83(17),

80(15),

79(24), 78(31),

77(36),

71(30),

69(21),

65(15),

57(45),

55(27),

51(18),

43(49),

42(48),

41(33),

29(25),

28(16),

18(20).

Daten

von

73:

(MeJjjN'

^^

^ß-

-N(Me)z

Ausbeute:

9

mg

=

0,03

mmol

=

13%

IH-NMR

(CDCI3,

200

MHz):

3,06

(2

s,

Iffl,

2

-N(CH3)2);

6,14-6,23

(m,

ffl,

H-C(4),

H-C(6));

6,72

(AA'

Oo

=

9,0),

ffl,

H-C(3%

H-C(5'));

735

(d

Oo

=

93),

IH,

H-C(3));

7,65

(XX'

0o

=

9,0),

ffl,

H-C(2'),

H-C(6'));

13,09

(s,

IH,

OH).

IR

(KBr):

2920m, 2850m,

2800w,

1630s, 1600s,

1555s,

1535s,

1475m,

1440m,

1395m, 1375m,

1340s,

1295s,

1260s,

1230m,

1200s,

1165s,

1125m,

1060m, 980w,

930m,

885m, 845w,

825m,

815m, 785m,

765m,

725w,

715w,

680m,

640w,

585w,

570m,

465w.

FAB

(I>10%):

285(23),

284(M+,

85),

283(20),

164(23),

148(16),

141(10),

128(17),

122(14),

121(100),

120(28).

1 2 ... 129 130 131 132 133 134 135 136 137 138 139 ... 167 168

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